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Sunday, June 17, 2018
| Time | Event | |
| 16:00 - 19:00 |
REGISTRATION - |
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| 19:00 - 21:00 | WELCOME MIXER - |
Monday, June 18, 2018
| Time | Event | |
| 09:00 - 09:15 |
INTRO&WELCOME- Didier GIGMES |
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| 09:15 - 10:00 | Plenary Lecture - Chair : Didier GIGMES | |
| 09:15 - 10:00 | › Sulfur Free RAFT polymerisation and polymerisation of acrylamides in water - David HADDLETON, Department of Chemistry, University of Warwick - UK | |
| 10:00 - 10:15 | Coffee break | |
| 10:15 - 10:45 | Invited Lecture - Chair : Didier GIGMES | |
| 10:15 - 10:45 | › Aspects of Catalysis in Single Electron Steps - Andreas GANSAUER, Kekulé-Institut für Organische Chemie und Biochemie der Universität Bonn, Bonn - Germany | |
| 10:45 - 11:15 | Invited Lecture - Chair : Didier GIGMES | |
| 10:45 - 11:15 | › Structural and Medium Effects on Hydrogen Atom Transfer Based Functionalization of Aliphatic C-H Bonds - Massimo BIETTI, Università di Roma “Tor Vergata”, Roma - Italy | |
| 11:15 - 11:30 | Oral Communication - Chair : Didier GIGMES | |
| 11:15 - 11:30 | › Mild and metal-free access to tetracyclic indoles and 7-azaindoles through Single Electron Transfer (SET) induced enolate arylation - Cherif ADOUAMA, Université Lyon 1, CNRS, INSA, CPE-Lyon, ICBMS, Lyon - France | |
| 11:30 - 12:00 | Invited Lecture - Chair : Didier GIGMES | |
| 11:30 - 12:00 | › New Horizons for Nitroxide Mediated Polymerization - José ASUA, POLYMAT University of the Basque Country, Donostia/San Sebastián - Spain | |
| 12:00 - 12:15 | Oral Communication - Chair : Didier GIGMES | |
| 12:00 - 12:15 | › Regenerable Preventive and Peroxyl Radical Trapping Ebselenamine Antoxidants - Vijay SINGH, Department of Chemistry & Centre for Advanced Studies in Chemistry, Chandigarh - India | |
| 12:15 - 14:00 | Lunch | |
| 14:00 - 14:45 | Plenary Lecture - Chair : Maurice MEDEBIELLE | |
| 14:00 - 14:45 | › Lipid Peroxidation, its Role in Cell Death and Slowing it with Small Molecules - Derek PRATT, Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa - Canada | |
| 14:45 - 15:15 | Invited Lecture - Chair : Maurice MEDEBIELLE | |
| 14:45 - 15:15 | › Air-stable Neutral Radicals with Spin-delocalized Structure: Full-cell Battery Application - Yasushi MORITA, Aichi Institute of Technology, Toyota - Japan | |
| 15:15 - 15:45 | Invited Lecture - Chair : Maurice MEDEBIELLE | |
| 15:15 - 15:45 | › Do Radical Enzymes Control the Reactivity of Reactive Intermediates using the Quantum Coulombic Effect? - Gino DILABIO, Department of Chemistry and Faculty of Management, The University of British Columbia, Kelowna, British Columbia - Canada | |
| 15:45 - 16:00 | Coffee break | |
| 16:00 - 16:30 | Invited Lecture - Chair : Emmanuel LACOTE | |
| 16:00 - 16:30 | › Photocontrolled Cationic Polymerizations of Vinyl Ethers - Brett FORS, Cornell University, Department of Chemistry and Chemical Biology, Ithaca, NY | |
| 16:30 - 16:45 | Oral Communication - Chair : Emmanuel LACOTE | |
| 16:30 - 16:45 | › Thiol Catalyzed Radical Deuteration with D2O: Mechanistic Insights - Valentin SOULARD, Universität Bern, Bern - Switzerland | |
| 16:45 - 17:15 | Invited Lecture - Chair : Emmanuel LACOTE | |
| 16:45 - 17:15 | › Redox catalysis strategies for complex molecules - Corey STEPHENSON, Willard Henry Dow Laboratory, Department of Chemistry, University of Michigan, Ann Arbor - USA | |
| 17:15 - 17:30 | Oral Communication - Chair : Emmanuel LACOTE | |
| 17:15 - 17:30 | › The Surprising Acidity of Radicals: Generality, Range and Applications - John WALTON, EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews - UK | |
| 17:30 - 18:00 | Invited Lecture - Chair : Emmanuel LACOTE | |
| 17:30 - 18:00 | › Tailored microstructured hyperpolarizing matrices for optimal magnetic resonance imaging - Chloe THIEULEUX, Laboratory C2P2 UMR 5265-CNRS-CPE Lyon-Univ. Lyon 1, Villeurbanne - France | |
| 18:00 - 18:15 | Oral Communication - Chair : Emmanuel LACOTE | |
| 18:00 - 18:15 | › The neglected reductive catalytic cycle of nitroxides with hydroperoxyl radicals - Luca VALGIMIGLI, University of Bologna, Bologna - Italy | |
| 18:15 - 19:30 | Break | |
| 19:30 - 23:30 | BANQUET |
Tuesday, June 19, 2018
| Time | Event | |
| 08:30 - 09:15 | Plenary Lecture - Chair : Armido STUDER | |
| 08:30 - 09:15 | › Harvesting Radicals to Functionalize π-Systems - Cristina NEVADO, University of Zurich, Department of Chemistry. Winterthurerstrasse 190, 8057 Zurich - Switzerland | |
| 09:15 - 09:45 | Invited Lecture - Chair : Armido STUDER | |
| 09:15 - 09:45 | › Organocobalt(III) based on Co(acac)2 as a source of alkyl radicals under mild conditions: application to the precision synthesis of unprecedented copolymers - Christophe DETREMBLEUR, Center for Education and Research on Macromolecules, CESAM Research Unit, University of Liege, Liege - Belgium | |
| 09:45 - 10:00 | Oral Communication - Chair : Armido STUDER | |
| 09:45 - 10:00 | › A new water-compatible N-heterocyclic Carbenes-Borane: photopolymerization efficiency, relationship between structure and reactivity - Berengere AUBRY, Institut de Science des Matériaux de Mulhouse (IS2M) - UMR CNRS 7361 – UHA – Université de Strasbourg, Mulhouse - France | |
| 10:00 - 10:15 | Coffee break | |
| 10:15 - 10:45 | Invited Lecture - Chair : Derek PRATT | |
| 10:15 - 10:45 | › Chemistry in living cells: covalent chemical capture for the discovery of new therapeutic targets - Anna MAPP, Life Sciences Institute, University of Michigan, Ann Arbor - USA | |
| 10:45 - 11:15 | Invited Lecture - Chair : Derek PRATT | |
| 10:45 - 11:15 | › KOtBu as Facilitator in Electron Transfer Reactions - John MURPHY, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow - UK | |
| 11:15 - 11:30 | Oral Communication - Chair : Derek PRATT | |
| 11:15 - 11:30 | › Antiferromagnetic Ordering Based on Dispersion Forces in Amphiphilic TEMPO Ammonium Salts - Jessica EXNER, Westfälische Wilhelms University Münster, Organic Chemistry Institute, Münster - Germany | |
| 11:30 - 12:00 | Invited Lecture - Chair : Derek PRATT | |
| 11:30 - 12:00 | › Site and Stereoselective Aliphatic C-H Oxidation with Biologically Inspired Catalysts - Miquel COSTAS, Institut de Quimica Computacional I Catàlisi, Facultat de Ciències, Universitat de Girona, Girona - Spain | |
| 12:00 - 12:15 | Oral Communication - Chair : Derek PRATT | |
| 12:00 - 12:15 | › Stereoselectivity of the radical cyclisation of alpha-bromaluminium acetals: New developments and Strategies to access pyrrolidines, pyrrolizidines and tetrahydrothiophene derivatives - Fabrice DENES, CEISAM, Université de Nantes, Nantes - France | |
| 12:15 - 14:00 | Lunch | |
| 14:00 - 14:45 | Plenary Lecture - Chair : Denis CURRAN | |
| 14:00 - 14:45 | › Electron Catalysis - Armido STUDER, Westfälische Wilhelms University Münster, Organic Chemistry Institute, Münster - Germany | |
| 14:45 - 15:15 | Invited Lecture - Chair : Denis CURRAN | |
| 14:45 - 15:15 | › Metalloradical Catalysis for Stereoselective Radical Chemistry - Peter ZHANG, Department of Chemistry, Boston College, Chestnut Hill - USA | |
| 15:15 - 15:45 | Invited Lecture - Chair : Denis CURRAN | |
| 15:15 - 15:45 | › Structural basis for semiquinone radical reactivity in bioenergetics enzymes: New insights from EPR spectroscopy, isotopic labeling and DFT calculations - Bruno GUIGLIARELLI, Bioénergétique et Ingénierie des Protéines, CNRS and Aix-Marseille University, Marseille | |
| 15:45 - 16:00 | Coffee break | |
| 16:00 - 16:30 | Invited Lecture - Chair : Michelle COOTE | |
| 16:00 - 16:30 | › Successful combination of RAFT and emulsion polymerization: from the formation of amphiphilic block copolymer particles to the synthesis of surfactant-free latexes - Muriel LANSALOT, Université Claude Bernard Lyon 1, CPE Lyon, UMR 5265, C2P2, Villeurbanne | |
| 16:30 - 16:45 | Oral Communication - Chair : Michelle COOTE | |
| 16:30 - 16:45 | › Homogeneous aerobic oxidation catalyzed by NHPI dervivatives: Co-solvent or not co-solvent, that is the question - Carlo PUNTA, Department of Chemistry, Materials, and Chemical Engineering “G. Natta”, Politecnico di Milano, Milano | |
| 16:45 - 17:15 | Invited Lecture - Chair : Michelle COOTE | |
| 16:45 - 17:15 | › Synthesis of Structurally Controlled Dendritic Hyperbranched Polymers by Radical Polymerization - Shigeru YAMAGO, Institute for Chemical Research, Kyoto University - Japan | |
| 17:15 - 17:30 | Oral Communication - Chair : Michelle COOTE | |
| 17:15 - 17:30 | › Kinetic Studies on the Effect of Metal Ions on Hydrogen Atom Transfer from Alkanols and Alkanediols to the Cumyloxyl Radical - Teo MARTIN, Dipartimento di Scienze e Tecnologie Chimiche, Università degli Studi di Roma “Tor Vergata”, Roma - Italy | |
| 17:30 - 18:00 | Invited Lecture - Chair : Michelle COOTE | |
| 17:30 - 18:00 | › New Transformations in Synthesis Enabled by Organic Photoredox Catalysis - David NICEWICZ, Department of Chemistry University of North Carolina at Chapel Hill, Chapel Hill - USA | |
| 18:00 - 18:30 | Invited Lecture - Chair : Michelle COOTE | |
| 18:00 - 18:30 | › Synthesis of Heterocycles through Electrochemical Dehydrogenative Cyclization and Annualtion Reactions - Hai-Chao XU, Xiamen University, Xiamen - China | |
| 18:30 - 19:45 | POSTER SESSION |
Wednesday, June 20, 2018
| Time | Event | |
| 08:30 - 09:15 | Plenary Lecture - Chair : Jacques LALEVEE | |
| 08:30 - 09:15 | › Photochemically Generated Radicals for Coupling, Functionalization and Polymerization Processes - Yusuf YAGCI, Istanbul Technical University, Department of Chemistry, Istanbul - Turkey | |
| 09:15 - 09:45 | Invited Lecture - Chair : Jacques LALEVEE | |
| 09:15 - 09:45 | › New radical cyclizations mediated by SmI2 - David PROCTER, School of Chemistry, University of Manchester, Manchester - UK | |
| 09:45 - 10:00 | Oral Communication | |
| 09:45 - 10:00 | › Charge-Transfer Complexes as a Linchpin for Transition Metal-Free Solar Light Assisted Synthesis - Alex SZPILMAN, Ariel University, Ariel - Israel | |
| 10:00 - 10:15 | Coffee break | |
| 10:15 - 10:45 | Invited Lecture - Chair : Philippe RENAUD | |
| 10:15 - 10:45 | › Recent Advances in Site-Selective C(sp3)-H Functionalization by Radicals - Ilhyong RYU, Department of Chemistry, Osaka Prefecture University, Osaka - Japan | |
| 10:45 - 11:15 | Invited Lecture - Chair : Philippe RENAUD | |
| 10:45 - 11:15 | › Taming CO2 reduction to methane. Fe based molecular complexes as catalysts, radicals (ions) as intermediates - Marc ROBERT, Université Paris Diderot, Sorbonne Paris Cité, Paris - France | |
| 11:15 - 11:30 | Oral Communication - Chair : Philippe RENAUD | |
| 11:15 - 11:30 | › Synthesis of alkylsulfonyl cyanides: Tin-free radical carbo- and sulfonyl-cyanation of olefins - Vincent PIRENNE, Institut des Sciences Moléculaires (ORGA) - Université de Bordeaux - France | |
| 11:30 - 12:00 | Invited Lecture - Chair : Philippe RENAUD | |
| 11:30 - 12:00 | › Organic radicals in metallic complexes: cooperative catalysis with redox-active ligands - Marine DESAGE-EL MURR, OMECA team, Université de Strasbourg, Strasbourg - France | |
| 12:00 - 12:15 | Oral Communication - Chair : Philippe RENAUD | |
| 12:00 - 12:15 | › Visible-Light-Mediated Photoredox-Catalyzed N-Arylation of NH-Sulfoximines with Electron-Rich Arenes - Alexander WIMMER, Departement of Chemistry and Pharmacy, Institute of Organic Chemistry, University of Regensburg, Regensburg - Germany | |
| 12:15 - 14:00 | Lunch | |
| 14:00 - 14:30 | Invited Lecture - Chair : Cristina NEVADO | |
| 14:00 - 14:30 | › New Macromolecular Designs for Nitroxide-Based MRI Contrast Agents: Enabling Metal-Free Tumor Imaging In Vivo - Jeremiah JOHNSON, MIT Department of Chemistry, Program in Polymers and Soft Matter, Koch Institute for Integrative Cancer Research, Cambridge - USA | |
| 14:30 - 15:00 | Invited Lecture - Chair : Cristina NEVADO | |
| 14:30 - 15:00 | › Functionalization of Olefins with Organic Radicals - Shunsuke CHIBA, Division of Chemistry and Biological Chemistry, Nanyang Technological University - Singapore | |
| 15:00 - 15:30 | Invited Lecture - Chair : Cristina NEVADO | |
| 15:00 - 15:30 | › Boosting NMR sensitivity: free radicals at work - Olivier OUARI, Institute of Free Radical Chemistry, Aix Marseille University / CNRS, Marseille - France | |
| 15:30 - 16:00 | Invited Lecture - Chair : Cristina NEVADO | |
| 15:30 - 16:00 | › Oxidative NHC-organocatalysis: what are the radical intermediates? - David MARTIN, Département de Chimie Moléculaire de Grenoble, Université Grenoble Alpes, Grenoble - France | |
| 16:00 - 16:15 | Coffee break | |
| 16:15 - 16:45 | Invited Lecture - Chair : Emmanuel LACOTE | |
| 16:15 - 16:45 | › The redox activity of nitroxides and their derivatives - Steven BOTTLE, CPME, Science and Engineering Faculty, Queensland University of Technology, (QUT), Brisbane - Australia | |
| 16:45 - 17:30 | Plenary Lecture - Chair : Emmanuel LACOTE | |
| 16:45 - 17:30 | › Electrostatic Catalysis of Radical Reactions - Michelle COOTE, ARC Centre of Excellence for Free-Radical Chemistry and Biotechnology, Research School of Chemistry, Australian National University, Canberra - Australia | |
| 17:30 - 17:45 |
CONCLUSION |
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